To unlock the three secret characters finish the story mode in vertical lane. They can ONLY be used in Player VS. COM mode and in the Arcade mode.
|Unlockable||How to unlock|
|Material L (Dark Hayate)||Finish the story lines of Hayate Reinforce and Shamal|
|Material M (Dark Fate)||Finish the story lines of Fate Signum and Chrono|
|Material S (Starlight Destroyer)||Finish the story lines of Nanoha Vita and Zafila|