| Unlockable | How to unlock |
|---|
| S. G. Yamamato | Do "Yamamato's Cooperation" In free time, or beat him in Bleach Tower, Level 4 |
| Shaolin Fong (Soi Fon) | Do "Soi fon's Cooperation" in free time, or beat her in Bleach Tower, Level 5 |
| Yoruichi Shihouin (Current) | Do "Yoruichi's Cooperation" in free time, or beat her in Bleach Tower, Level 5 |
| Yoruichi Shihouin (Former) | Beat her in Bleach Tower, in the level she's in with Kisuke Urahara |
| Gin Ichimaru | Beat him in 5 turns (before Izuru) in Bleach Tower, Level 6 |
| Izuru Kira | Do "Izuru's Cooperation" in free time, or beat him in Bleach Tower, Level 6 |
| Retsu Unohana | Do "Unohana's Cooperation" In free time, or beat her in Bleach Tower, Level 7 |
| Hanatarou Yamada | Do "Hanatarou's Cooperation" in free time, or beat him in Bleach Tower, Level 7 |
| Hinamori Momo | Do "Hinamori's Cooperation" in free time, or beat her in Bleach Tower, Level 8 |
| Byakuya Kuchiki | Do "Byakuya's Cooperation" in free time, or beat him in Bleach tower, Level 9 |
| Renji Abarai | Do "Renji's Cooperation" in free time, or beat him in Bleach Tower, Level 9 |
| Sajin Komamura | Do "Komamura's Cooperation" In free time, or beat him in Bleach Tower, Level 10 |
| Shunsui Kyoraku | Do "Kyoraku's Cooperation" in free time, or beat him in Bleach Tower, Level 11 |
| Kaname Tousen | Beat him in Bleach Tower, Level 12 |
| Shuuhei Hisagi | Do "Hisagi's Cooperation" in free time, or beat him in Bleach Tower, Level 12 |
| Kusaka | Bleach Tower Stage 21. Have Hitsugaya to attack him and complete the stage |
| Ikkaku | Defeat him on a one on one fight with your main character In "Ikkaku's cooperation" in free time |
| Yumichika | Unlocked after telling Yumichika he looks like the type to like a fight in "Yumichika's cooperation" in free time |
| Kempachi Zeraki | After Recruiting Ikkaku and Yumichika talk to yauchiru in free time afterwards defeat Kempachi in "Kempachi and Yauchiru's cooperation" in free time |
| Yauchiru | Unlocked with Kempachi |
| Sousuke Aizen | Complete floor 30 of Urahada's tower |
| Grimjoww JaggurJaque | Complete floor 30 or Urahada's tower |
